%nprocshared=32
%chk=PhO2S-F.chk
#p opt freq wb97xd/genecp scrf=(smd,solvent=acetonitrile)

wwww

0 1
 S                  0.98598374    0.17362597    0.31831472
 C                 -0.77372479   -0.04736150    0.16668868
 O                  1.50742853    0.80459484   -0.90221704
 O                  1.27390951    1.03279642    1.47531473
 C                 -1.63843179    0.56494882    1.08390175
 C                 -1.29444223   -0.83365601   -0.86990007
 C                 -3.02385647    0.39096822    0.96452346
 H                 -1.24085232    1.16529969    1.87536205
 C                 -2.67986678   -1.00763859   -0.98927693
 H                 -0.63421916   -1.30116975   -1.57021172
 C                 -3.54457397   -0.39532537   -0.07206596
 H                 -3.68407948    0.85848104    1.66483578
 H                 -3.07744606   -1.60799267   -1.78073488
 H                 -4.60237647   -0.52816321   -0.16321409
 F                  1.68217829   -1.24119717    0.52249266

-B -F -K -C -H -O -F -S -N
6-311G++(d,p)
*****




