%nprocshared=20
%mem=16GB
%chk=ts_S2_insertion_ring4.chk
#p opt(ts,calcfc,noeigentest) freq wb97xd/gen scrf=(smd,solvent=n,n-dimethylformamide)

Title Card Required

-1 1
 C     3.814672    -0.798412    -1.218915
 C     2.971451     0.665187     0.166430
 O     2.990964     1.248343     1.211864
 C     2.893864    -0.775337    -0.234827
 S     1.078066     1.453967    -1.079733
 S     4.410518     0.844864    -1.326282
 C     2.029865    -1.798855     0.352005
 C     1.928685    -3.073608    -0.227123
 C     1.279533    -1.521182     1.503188
 C     1.107507    -4.042908     0.336793
 H     2.492714    -3.303267    -1.126796
 C     0.457169    -2.495085     2.063254
 H     1.343701    -0.536974     1.955625
 C     0.367652    -3.759313     1.485264
 H     1.040956    -5.023853    -0.124608
 H    -0.114900    -2.262685     2.956548
 H    -0.274894    -4.517343     1.922786
 S     0.434769     2.905228     0.180860
 S    -0.498941     2.097844     1.870318
 S    -2.480472     1.648280     1.355974
 S    -2.680378    -0.409921     1.370480
 S    -2.010166    -1.160230    -0.478097
 S    -3.524357    -1.031342    -1.785001
 F    -3.340768     0.467014    -2.450630
 H     4.146353    -1.624282    -1.838882

-O C H S F
6-31g(d,p)
******





