%nprocshared=32
%mem=16GB
%chk=ts2_h_ph.chk
#p opt=(calcfc,ts,noeigentest) freq wb97xd/gen
scrf=(smd,solvent=n,n-dimethylformamide)

Title Card Required

0 3
 C                    -2.13731  -2.78228   0.69021 
 C                    -2.02757  -2.48491  -0.72419 
 C                    -2.72944  -1.62802   0.12488 
 S                    -0.24638   0.20917  -1.72164 
 S                     0.12135  -1.63464  -1.00254 
 O                    -1.899    -3.51344   1.62688 
 H                    -2.11998  -2.87523  -1.73161 
 C                    -3.53841  -0.44896   0.17981 
 C                    -3.94808   0.06407   1.42386 
 C                    -3.8878    0.22087  -1.00777 
 C                    -4.69012   1.23454   1.47439 
 H                    -3.67175  -0.45933   2.33373 
 C                    -4.62776   1.39272  -0.94569 
 H                    -3.57533  -0.18768  -1.96391 
 C                    -5.02624   1.89913   0.29272 
 H                    -5.00557   1.63571   2.43187 
 H                    -4.8962    1.91395  -1.85864 
 H                    -5.60401   2.81709   0.33762 
 
-O C H S
6-31g(d,p)
******





