%nprocshared=32
%mem=16GB
%chk=ts2_h_ph.chk
#p opt=(calcfc,ts,noeigentest) freq wb97xd/gen
scrf=(smd,solvent=n,n-dimethylformamide)

Title Card Required

0 3
 C                     2.22642   1.29773   2.25031 
 C                     2.54905   0.42945   1.09013 
 C                     2.24469  -0.09563   2.35962 
 S                     0.34511  -1.28935  -0.66517 
 S                     0.63878   0.60832  -0.04479 
 O                     2.10632   2.41442   2.69421 
 C                     3.58335   0.132     0.08493 
 C                     4.09563   1.1539   -0.721 
 C                     4.06201  -1.17415  -0.04876 
 C                     5.08854   0.86784  -1.65028 
 H                     3.71403   2.16509  -0.61503 
 C                     5.04987  -1.4566   -0.98806 
 H                     3.66496  -1.9616    0.58534 
 C                     5.56322  -0.43724  -1.7871 
 H                     5.49126   1.66158  -2.27151 
 H                     5.42055  -2.47133  -1.09304 
 H                     6.33576  -0.65799  -2.51723 
 H                     2.37773  -0.97751   2.9739 

-O C H S
6-31g(d,p)
******





