%nprocshared=32
%mem=16GB
%chk=ts_SF_insertion_ring4.chk
#p opt=(calcfc,ts,noeigentest) freq wb97xd/gen
scrf=(smd,solvent=n,n-dimethylformamide)

Title Card Required

-1 1
 C                  3.76536200    0.79845500    1.14487000
 C                  2.86605800   -0.69801300   -0.17195300
 O                  2.85087500   -1.30389800   -1.20442300
 C                  2.80697100    0.75164000    0.19824300
 S                  1.03336700   -1.46019300    1.16052000
 S                  4.36947200   -0.83965500    1.27205300
 C                  1.91935700    1.76095900   -0.37803200
 C                  1.83888300    3.04869100    0.17516700
 C                  1.12493500    1.45662000   -1.49235300
 C                  0.99489200    4.00430900   -0.37830700
 H                  2.43717800    3.29932600    1.04665900
 C                  0.27979600    2.41689700   -2.04196800
 H                  1.17280000    0.46242200   -1.92452200
 C                  0.21104700    3.69402500   -1.49011700
 H                  0.94500300    4.99554500    0.06276500
 H                 -0.32641600    2.16364500   -2.90662400
 H                 -0.44926700    4.44141800   -1.91940500
 H                  4.11878700    1.64046300    1.73029100
 F                  0.34470100   -2.94158700   -0.03938400

-O C H S F
6-31g(d,p)
******






