%nprocshared=32
%mem=16GB
%chk=ts2_s2F_h_ph.chk
#p opt=(calcfc,ts,noeigentest) freq wb97xd/gen
scrf=(smd,solvent=n,n-dimethylformamide)

Title Card Required

-1 1
 C                  3.08906500   -1.74804100   -0.01518000
 C                  4.57042200   -1.72026300   -1.07796600
 O                  5.15547300   -2.49283900   -1.79321100
 C                  4.11246600   -0.72263700   -0.35389500
 S                  0.19445100   -0.33060100   -0.21386900
 S                  1.56929500   -1.88211900   -0.83389300
 C                  4.41924900    0.62863700    0.06859700
 C                  3.60466300    1.27733500    1.01042600
 C                  5.53295300    1.32274800   -0.43806100
 C                  3.89141500    2.57284400    1.42892100
 H                  2.73937100    0.75251600    1.40659700
 C                  5.81460100    2.61727900   -0.01651600
 H                  6.17599200    0.83686600   -1.16757200
 C                  4.99698600    3.25294000    0.91922800
 H                  3.24576300    3.05516700    2.15796100
 H                  6.67965700    3.13519600   -0.42197800
 H                  5.21884300    4.26464400    1.24512100
 H                  3.12067200   -2.24938400    0.95427000
 F                 -0.41853562   -0.75174336    1.25901474

-O C H S F
6-31g(d,p)
******





