%nprocshared=32
%mem=16GB
%chk=ts2_s2F_h_ph.chk
#p opt=(calcfc,ts,noeigentest) freq wb97xd/gen
scrf=(smd,solvent=n,n-dimethylformamide)

Title Card Required

-1 1
 C                     1.45434   4.19953   0.57962 
 C                     2.33778   3.47399   1.37714 
 C                     2.70751   2.18193   1.01818 
 C                     2.18127   1.58956  -0.13562 
 C                     1.29196   2.32104  -0.92978 
 C                     0.93805   3.62068  -0.57692 
 C                     2.57253   0.21578  -0.53683 
 C                     2.80219  -0.77366   0.37164 
 O                     3.17893  -1.69007   0.95812 
 C                     2.78525  -0.16631  -1.8911 
 S                     3.18277  -1.65125  -2.5153 
 S                     0.54751  -0.16003   2.33074 
 H                     3.41155   1.63175   1.63584 
 H                     0.86206   1.87028  -1.8195 
 H                     2.75019   3.91836   2.27788 
 H                     0.24504   4.17476  -1.2028 
 H                     1.1709    5.20977   0.85836 
 H                     2.66836   0.6692   -2.58471 
 F                     0.00558  -1.65482   2.33414 
 
-O C H S F
6-31g(d,p)
******





