%nprocshared=32
%mem=16GB
%chk=ts2_s2F_h_ph.chk
#p opt=(calcfc,ts,noeigentest) freq wb97xd/gen
scrf=(smd,solvent=n,n-dimethylformamide)

Title Card Required

-1 1
 C                     6.7681   -0.39557  -1.07127 
 C                     6.18925   0.77124  -0.57717 
 C                     4.90413   0.7525   -0.04176 
 C                     4.15983  -0.437     0.0075 
 C                     4.74854  -1.60085  -0.51541 
 C                     6.03886  -1.58262  -1.03557 
 C                     2.79065  -0.4931    0.58696 
 C                     1.92233   0.67041   0.32319 
 O                     2.12221   1.82767   0.58719 
 C                     2.3762   -1.55664   1.34662 
 S                     0.9145   -1.81739   2.20817 
 S                     0.44403   0.1864   -0.68886 
 H                     4.47502   1.66695   0.353 
 H                     4.18104  -2.52697  -0.52933 
 H                     6.7442    1.70497  -0.59857 
 H                     6.46877  -2.49867  -1.43082 
 H                     7.77198  -0.37932  -1.48469 
 H                     3.14022  -2.32819   1.47187 
 F                    -0.29603   1.69725  -1.02847 

-O C H S F
6-31g(d,p)
******





