%nprocshared=32
%mem=16GB
%chk=ts_3_H_ph.chk
#p opt=(calcfc,ts,noeigentest) freq wb97xd/gen
scrf=(smd,solvent=n,n-dimethylformamide)

Title Card Required

0 1
 C                 -2.99957999    0.62840982    1.12001685
 C                 -2.99062929   -0.01350537   -1.22897190
 O                 -2.95301048   -0.43283282   -2.29274317
 C                 -3.28332400    0.87003800   -0.19123100
 S                  0.38497500   -1.57214600   -0.05893700
 S                 -1.74273971   -1.88691149    0.26540395
 S                  0.44286800    0.26027500   -1.06944700
 S                  0.70534200    1.73884700    0.31702400
 S                  2.78572000    1.54521100    0.94282300
 S                  3.71813600    0.46418400   -0.53937000
 S                  3.36515800   -1.53825600   -0.18975000
 S                 -2.24154907   -0.70140509    1.88528475
 H                 -3.31048801    1.38363849    1.84140196
 C                 -3.96626926    2.15456575   -0.69637873
 C                 -4.21996935    2.32037624   -2.05822107
 C                 -4.33130548    3.15218345    0.20753256
 C                 -4.83795994    3.48386822   -2.51603741
 H                 -3.93136401    1.53402303   -2.77067975
 C                 -4.95038427    4.31566119   -0.25014732
 H                 -4.13158575    3.02158512    1.28093143
 C                 -5.20362632    4.48170788   -1.61170304
 H                 -5.03739397    3.61490635   -3.58951381
 H                 -5.23845952    5.10188971    0.46282644
 H                 -5.69093092    5.39896773   -1.97290235

-O C H S
6-31g(d,p)
******



