%nprocshared=32
%mem=36GB
%chk=s2_trip_s6cyc_TS.chk
#p opt=(calcfc,ts,noeigentest) freq uwb97xd/gen
scrf=(smd,solvent=n,n-dimethylformamide)

Title Card Required

0 3
 C                 -1.81350354   -2.91945386    0.45775667
 C                 -1.70376254   -2.62208086   -0.95663933
 C                 -2.40563354   -1.76519986   -0.10756433
 S                  0.07743046    0.07199114   -1.95408633
 S                  0.44516046   -1.77181886   -1.23498933
 S                 -0.16086747    1.52081332   -0.11528020
 S                  1.32436286    2.77240390    0.27964971
 S                  2.71725686    1.79931690    1.49675171
 S                  1.65318897    1.52343565    3.18764313
 S                 -0.32957419    2.15635472    3.24654275
 S                 -1.60642211    2.07268762    1.80704908
 O                 -1.57518754   -3.65061986    1.39443467
 H                 -1.79617354   -3.01240086   -1.96405333
 C                 -3.21459954   -0.58613186   -0.05263433
 C                 -3.62427054   -0.07310986    1.19141167
 C                 -3.56398754    0.08369414   -1.24022233
 C                 -4.36630954    1.09736414    1.24194267
 H                 -3.34793854   -0.59650886    2.10128067
 C                 -4.30395254    1.25554214   -1.17814033
 H                 -3.25152154   -0.32485786   -2.19635533
 C                 -4.70243054    1.76195314    0.06027467
 H                 -4.68176054    1.49853314    2.19942167
 H                 -4.57239354    1.77677414   -2.09108833
 H                 -5.28019554    2.67990914    0.10516867

-O C H S
6-31g(d,p)
******





