%nprocshared=32
%mem=16GB
%chk=ts1_crest_s8_h_ph.chk
#p opt=(calcfc,ts,noeigentest) freq wb97xd/gen
scrf=(smd,solvent=n,n-dimethylformamide)

Title Card Required

0 1
 C                 -2.90141627   -0.12506361    1.52293718
 C                 -3.20103228   -0.53492480   -0.42645474
 C                 -3.94478600   -0.09319400    0.62154700
 O                 -2.01787357   -0.17000119    2.25602574
 H                 -3.70544784   -0.66214378   -1.39077751
 S                 -0.96496600   -1.35144000   -0.68122200
 S                  1.04350800   -2.29798100   -0.95851900
 S                 -0.72300100    0.32011000   -1.90323500
 S                  2.05220700   -1.93116500    0.80095900
 S                 -0.47458300    1.96512800   -0.67197200
 S                  3.30196100   -0.28845100    0.54635200
 S                  1.55403500    2.38039000   -0.50012100
 S                  2.30471000    1.42013000    1.18275100
 C                 -5.40544025    0.32271300    0.87671464
 C                 -6.36428735    0.15077585   -0.12204524
 C                 -5.76985790    0.87119135    2.10631596
 C                 -7.68709362    0.52788461    0.10859362
 H                 -6.07651230   -0.28095053   -1.09160165
 C                 -7.09322440    1.24755515    2.33753290
 H                 -5.01430041    1.00661009    2.89366828
 C                 -8.05179993    1.07612763    1.33889254
 H                 -8.44279621    0.39297290   -0.67881285
 H                 -7.38034305    1.67959959    3.30726209
 H                 -9.09485816    1.37333564    1.52053302

-O C H S
6-31g(d,p)
******




