%nprocshared=32
%mem=16GB
%chk=ts1_crest_s8_ph_h.chk
#p opt=(calcfc,ts,noeigentest) freq wb97xd/gen
scrf=(smd,solvent=n,n-dimethylformamide)

Title Card Required

0 1
 C                 -2.90115462   -0.12383512    1.52263825
 C                 -3.20103228   -0.53492480   -0.42645474
 C                 -3.94426616   -0.09098990    0.62098430
 O                 -2.01785441   -0.16962581    2.25596620
 S                 -0.96496600   -1.35144000   -0.68122200
 S                  1.04350800   -2.29798100   -0.95851900
 S                 -0.72300100    0.32011000   -1.90323500
 S                  2.05220700   -1.93116500    0.80095900
 S                 -0.47458300    1.96512800   -0.67197200
 S                  3.30196100   -0.28845100    0.54635200
 S                  1.55403500    2.38039000   -0.50012100
 S                  2.30471000    1.42013000    1.18275100
 H                 -4.95868141    0.19987405    0.79778886
 C                 -3.90999144   -0.71373186   -1.78181630
 C                 -5.28048366   -0.47550407   -1.88891452
 C                 -3.18202168   -1.11372911   -2.90235651
 C                 -5.92290371   -0.63791499   -3.11616385
 H                 -5.85426051   -0.16090925   -1.00514306
 C                 -3.82430441   -1.27528181   -4.13027488
 H                 -2.10182018   -1.30136015   -2.81816435
 C                 -5.19455284   -1.03758797   -4.23731641
 H                 -7.00325401   -0.45076691   -3.20051623
 H                 -3.24999917   -1.59027396   -5.01369305
 H                 -5.70128408   -1.16552052   -5.20486643

-O C H S
6-31g(d,p)
******




