%nprocshared=32
%mem=36GB
%chk=3ts1n.chk
#p opt=(calcfc,ts,noeigentest) freq uwb97xd/gen
scrf=(smd,solvent=n,n-dimethylformamide)

Title Card Required

0 3
 C                    -2.13731  -2.78228   0.69021 
 C                    -2.02757  -2.48491  -0.72419 
 C                    -2.72944  -1.62802   0.12488 
 S                    -0.24638   0.20917  -1.72164 
 S                     0.12135  -1.63464  -1.00254 
 S                    -0.45937   1.50678  -0.07505 
 S                     1.239     2.67754   0.03695 
 S                     2.63189   1.70445   1.25405 
 S                     4.1687    1.0707    0.03589 
 S                     3.66703  -0.86593  -0.68443 
 S                     3.61161  -2.13931   0.80592 
 O                    -1.899    -3.51344   1.62688 
 C                    -2.15882  -3.03925  -2.15495 
 C                    -1.19536  -3.91605  -2.65439 
 C                    -3.24091  -2.66489  -2.9515 
 C                    -1.31369  -4.4178   -3.95034 
 H                    -0.34197  -4.21039  -2.02643 
 C                    -3.35994  -3.16747  -4.24751 
 H                    -4.00045  -1.97398  -2.55795 
 C                    -2.3965   -4.04369  -4.74707 
 H                    -0.55399  -5.10841  -4.34429 
 H                    -4.21345  -2.87245  -4.87518 
 H                    -2.48962  -4.43948  -5.76882 
 H                    -3.34565  -0.7299    0.16673

-O C H S
6-31g(d,p)
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