%mem=16GB
%chk=CuxantBpin.chk
#p opt freq wb97xd/genecp scrf=(solvent=thf,smd) 

Title Card Required

0 1
 C                 -2.30434000   -0.84555500   -0.92634300
 C                 -1.29230600   -1.69509400   -1.37382500
 C                 -1.43434100   -2.56884400   -2.44894000
 C                 -2.66424200   -2.56855200   -3.10723100
 C                 -3.70035400   -1.73859400   -2.68418500
 C                 -3.52741000   -0.88571800   -1.59779800
 H                 -2.82610500   -3.22488200   -3.95550100
 H                 -4.65139800   -1.75812700   -3.20651800
 H                 -4.33978100   -0.23998600   -1.28032400
 C                 -0.26002300   -3.49402700   -2.76756300
 C                  1.02287800   -2.70195500   -2.51066500
 C                  1.03492400   -1.81443500   -1.43505900
 C                  2.20415300   -2.83501100   -3.23816500
 C                  2.15345800   -1.06949300   -1.05508500
 C                  3.34282700   -2.11448900   -2.88555300
 H                  2.24480700   -3.50808500   -4.08757500
 C                  3.32092400   -1.24002500   -1.80413600
 H                  4.25448700   -2.23257100   -3.46224500
 H                  4.21171100   -0.67387300   -1.55490300
 O                 -0.10385500   -1.64140200   -0.68688300
 P                 -1.88009800    0.31198800    0.43925600
 P                  1.94573400    0.18746800    0.28212700
 Cu                 0.04953500    1.60696100   -0.17308900
 B                  0.01736500    3.44814000   -1.09571000
 O                 -0.94317900    3.86730900   -2.02642300
 O                  0.92878200    4.49209200   -0.88907400
 C                 -0.74487600    5.24792300   -2.33869300
 C                  0.64625900    5.56753300   -1.78730000
 C                 -1.82841700   -0.77870500    1.91913000
 C                 -1.28057300   -0.23776100    3.08736900
 C                 -2.30280800   -2.09285300    1.93207900
 C                 -1.22961000   -0.99060900    4.25537900
 H                 -0.88871200    0.77653300    3.08094500
 C                 -2.23398800   -2.85214200    3.09820300
 H                 -2.72947400   -2.52736700    1.03278400
 C                 -1.70313800   -2.30124500    4.26142700
 H                 -0.80284900   -0.56029900    5.15573800
 H                 -2.60062100   -3.87427300    3.09696700
 H                 -1.65137100   -2.89357900    5.16997900
 C                  2.01805200   -0.78125100    1.85064900
 C                  2.30140500   -0.08150600    3.03128900
 C                  1.74419700   -2.14850400    1.92371400
 C                  2.33809900   -0.74302800    4.25381500
 H                  2.51077100    0.98467200    2.99415900
 C                  1.76742500   -2.80643100    3.15186800
 H                  1.52130400   -2.71451400    1.02548800
 C                  2.07154500   -2.10955600    4.31727200
 H                  2.57234900   -0.18915300    5.15796500
 H                  1.55092800   -3.86959300    3.19276100
 H                  2.09487200   -2.62662000    5.27169000
 C                  3.57140500    1.05012600    0.29680500
 C                  3.63047900    2.35852400   -0.19137000
 C                  4.74041500    0.43998300    0.77158800
 C                  4.84486200    3.04351800   -0.21260400
 H                  2.72535800    2.84889800   -0.54241300
 C                  5.94950000    1.12626300    0.74912300
 H                  4.70329600   -0.57414800    1.15941000
 C                  6.00289600    2.42996700    0.25513300
 H                  4.88032800    4.06107600   -0.59000600
 H                  6.85036800    0.64528800    1.11801000
 H                  6.94702700    2.96636100    0.24072700
 C                 -3.44302800    1.25771400    0.66199700
 C                 -3.57117200    2.46843600   -0.02906800
 C                 -4.49589900    0.81123700    1.46750000
 C                 -4.74200700    3.21510400    0.07946200
 H                 -2.75361100    2.82743100   -0.65106500
 C                 -5.66043400    1.56564300    1.58097600
 H                 -4.40736000   -0.12567600    2.00960000
 C                 -5.78571500    2.76714000    0.88589700
 H                 -4.83400800    4.15211200   -0.46158700
 H                 -6.47101300    1.21382800    2.21209800
 H                 -6.69480600    3.35429100    0.97570100
 C                 -0.30218900   -4.68215700   -1.77705400
 H                 -1.22500400   -5.25477700   -1.91567600
 H                  0.55078600   -5.34674100   -1.94835700
 H                 -0.26680500   -4.33857500   -0.73858700
 C                 -0.32461800   -4.03404800   -4.19779300
 H                 -0.29974100   -3.22721900   -4.93649200
 H                  0.51165300   -4.71063500   -4.39232000
 H                 -1.23784400   -4.61582000   -4.34771100
 C                 -1.84263925    6.08542434   -1.65670521
 H                 -1.80481517    7.08977070   -2.02379882
 H                 -2.80099327    5.66208860   -1.87406305
 H                 -1.68484059    6.08631375   -0.59840526
 C                  0.69695706    6.90788829   -1.03067763
 H                  1.70985402    7.13083582   -0.76755383
 H                  0.31158979    7.68553250   -1.65650632
 H                  0.10465260    6.83858195   -0.14226778
 C                  1.71416594    5.59735034   -2.89648244
 H                  1.59072966    6.48122318   -3.48676396
 H                  2.68829827    5.59725485   -2.45380175
 H                  1.60545685    4.73429017   -3.51954703
 C                 -0.84927290    5.46098761   -3.86030555
 H                 -1.85798551    5.29354251   -4.17552136
 H                 -0.56223281    6.46336391   -4.10061729
 H                 -0.20013583    4.77409471   -4.36200188

-Cu 0
 lanl2dz
 F    1 1.00
 3.5250000           1.0
 ****
 -P
 lanl2dz
 D    1 1.00
 0.3870000           1.0
 ****
 -O C H B
 6-31g(d,p)
 ******

 -Cu 1
 lanl2dz
 -P
 lanl2dz









