%mem=16GB
%chk=R1a-giro.chk
#p opt freq wb97xd/genecp scrf=(smd,solvent=tetrahydrofuran)

Title Card Required

0 1
 C                 -0.77922194    2.18775608   -2.83041592
 H                 -1.85064485    2.22222365   -3.01777886
 H                 -0.12557387    2.40579145   -3.67064737
 C                 -0.29246050    1.89040352   -1.62858390
 H                  0.78604893    1.87432030   -1.47125532
 C                 -1.12659900    1.58319400   -0.41220800
 H                 -2.09972326    2.06925088   -0.50658090
 C                 -0.30852500   -0.78495300   -0.12905900
 C                 -1.32900600    0.08729400   -0.25509200
 C                  3.22182700    0.57050700   -0.23361300
 C                  3.42771700   -0.93157400    0.16431500
 O                  1.80367500    0.75296800   -0.00969400
 O                  2.13257900   -1.50632400   -0.12356900
 B                  1.21427600   -0.48623100   -0.09289000
 C                  3.47524000    0.84024600   -1.71662500
 H                  3.11850400    1.84477500   -1.96094800
 H                  4.54123700    0.78715400   -1.95517100
 H                  2.94022400    0.12580300   -2.34951600
 C                  4.48678000   -1.66409800   -0.64507000
 H                  5.46399600   -1.18888400   -0.51318900
 H                  4.56430100   -2.69962600   -0.30115900
 H                  4.24442100   -1.67650100   -1.70957500
 C                  3.67817000   -1.12741800    1.65963700
 H                  3.61160200   -2.19350300    1.89408600
 H                  4.67206300   -0.77372600    1.94809500
 H                  2.93188900   -0.60005400    2.26153400
 C                  3.98757700    1.56922900    0.61985900
 H                  5.06475700    1.39273100    0.53848800
 H                  3.78312700    2.58602500    0.27210400
 H                  3.70111400    1.50533200    1.67145300
 H                 -0.57549800   -1.83934800   -0.04629200
 C                 -2.74308500   -0.38534200   -0.19188000
 C                 -3.24691611   -1.31763306   -1.10873494
 C                 -3.60899855    0.10754978    0.79392792
 C                 -4.56356952   -1.76076625   -1.02597022
 H                 -2.60388642   -1.71982518   -1.88525325
 C                 -4.92771128   -0.32875610    0.87290392
 H                 -3.24801223    0.85685862    1.49219636
 C                 -5.40991028   -1.26813119   -0.03547390
 H                 -4.92872274   -2.49384893   -1.73911290
 H                 -5.58165832    0.07265932    1.64132525
 H                 -6.43909139   -1.60898719    0.02386198
 C                 -0.43569341    2.15632791    0.83909811
 C                  0.01523065    3.47659923    0.84384899
 C                 -0.26080849    1.35559762    1.96772311
 C                  0.64149178    3.99573383    1.97677352
 H                 -0.12210730    4.10738615   -0.04636892
 C                  0.36474131    1.87503893    3.10142415
 H                 -0.61630588    0.31505049    1.96421330
 C                  0.81600749    3.19483976    3.10607840
 H                  0.99750335    5.03618533    1.98037008
 H                  0.50212464    1.24358893    3.99129545
 H                  1.30976796    3.60439586    3.99925291

 -Cu
 lanl2dz
 F    1 1.00
 3.5250000           1.0
 ****
 -P
 lanl2dz
 D    1 1.00
 0.3870000           1.0
 ****
 -O C H B
 6-31g(d,p)
 ******

 -Cu 1
 lanl2dz
 -P
 lanl2dz





