%mem=50GB
#p scf=xqc optcyc=800 opt=(calcfc,noeigentest,ts) freq b3lyp/genecp scrf=(solvent=h2o,pcm)
 
POM Co

-5 2
  8           0        1.214860   -0.325598    1.128777
 Co           0        1.202620    0.344155    3.433588
  8           0        1.753053   -1.643465    3.378996
 74           0        1.914674   -2.533790    1.826473
  8           0        3.495968   -1.532590    1.301309
 74           0        3.538045    0.353889    0.908013
  8           0        3.199141    0.796217    2.652470
 15           0        0.049918   -0.006991    0.110069
  8           0       -0.123983    1.565114   -0.045419
 74           0        1.597153    3.076277   -0.820533
  8           0        0.775313    3.851475    0.715565
 74           0       -0.670662    3.068830    1.808911
  8           0       -1.801515    3.525967    0.184627
 74           0       -1.758567    2.711379   -1.499532
  8           0       -3.005113    1.374452   -0.895667
 74           0       -3.515796   -0.445114   -0.519945
  8           0       -3.782598   -0.033243    1.270835
 74           0       -2.395983   -0.026324    2.790824
  8           0       -2.050286    1.783947    2.222869
  8           0        2.614484   -4.035318    2.307724
  8           0        1.711069   -2.919719   -0.153647
 74           0        0.738431   -2.990732   -1.738372
  8           0       -0.443775   -2.291279   -3.134122
 74           0       -1.026801   -0.471318   -3.316970
  8           0        0.789138   -0.047869   -3.817889
 74           0        2.339674   -0.080412   -2.644645
  8           0        2.135736   -2.001569   -2.652313
  8           0        0.002258   -2.954059    1.794635
 74           0       -1.740600   -2.958165    1.027190
  8           0       -3.227944   -2.285344   -0.014932
  8           0        1.031597   -4.583168   -2.324800
  8           0        0.370873   -0.626965   -1.321037
  8           0       -0.829168   -3.236954   -0.655833
  8           0        3.621147    0.121921   -3.776474
  8           0        1.923980    1.739151   -2.173311
  8           0        3.224601   -0.177316   -0.996480
  8           0       -2.295386   -4.544605    1.392794
  8           0       -1.320402   -0.611207    0.641215
  8           0       -2.452987   -1.972463    2.503365
  8           0        2.630372    4.353192   -1.330089
  8           0        2.764621    2.029230    0.277487
  8           0       -0.024195    3.510632   -1.786426
  8           0        5.229745    0.646197    0.788683
  8           0       -2.763845    3.742854   -2.440709
  8           0       -1.241970    1.357932   -2.793301
  8           0       -1.089584    4.413478    2.806009
  8           0        0.516648    2.151200    2.789319
  8           0       -3.511377    0.172178    4.093563
  8           0       -0.812221   -0.128728    3.612442
  8           0       -5.119706   -0.508288   -1.140343
  8           0       -2.457092   -0.838605   -2.116978
  8           0       -1.801095   -0.510596   -4.853671
  8           0        1.854376    0.789213    5.138945
  8           0        3.437900    1.302051    5.025789
  1           0        3.873666    0.562886    5.483701
  1           0        3.520218    1.119886    3.975490

-W -P -Co 0 
lanl2dz
****
-H -O 0 
6-31g(d,p)
****

-W -P -Co 0 
lanl2dz



